Abstract
Organic solvents are extensively used in organic synthesis and for this reason they are a matter of much concern due to characteristics such as: high flammability, volatility, hazardness, and toxicity. Thus the search for environmentally benign substitutes for organic solvents has recently gained more attention in view of the increasing importance of Green Chemistry. In this review, recent developments in the fields of supercritical fluids, ionic liquids, low melting polymers (especially PEG), perfluorinated solvents and water in many types of organic reactions will be disclosed.
Keywords: organic reaction, dissolution, solubility, hydrolysis, metal-mediated allylation
Call for Papers in Thematic Issues
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This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
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