Abstract
Chiral organoselenium compounds can be attained from three types of asymmetric synthesis. Chiral substratecontrolled methods, chiral auxiliary-controlled methods, and chiral catalyst-controlled methods toward optically active organoselenium derivatives were illustrated. The strategy and classification of methods underlying all asymmetric synthesis therefore involve enantiomerically pure compounds to influence the stereochemical outcome of the reactions. In this review, the advances in asymmetric synthesis of some important classes of chiral organoselenium compounds were described.
Keywords: Prochiral Olefin, Selenocyclization, regioselectivity, ammonium persulfate, Seleno Alcohols
Current Organic Chemistry
Title: Asymmetric Synthesis of Chiral Organoselenium Compounds
Volume: 10 Issue: 15
Author(s): Chengjian Zhu and Yijun Huang
Affiliation:
Keywords: Prochiral Olefin, Selenocyclization, regioselectivity, ammonium persulfate, Seleno Alcohols
Abstract: Chiral organoselenium compounds can be attained from three types of asymmetric synthesis. Chiral substratecontrolled methods, chiral auxiliary-controlled methods, and chiral catalyst-controlled methods toward optically active organoselenium derivatives were illustrated. The strategy and classification of methods underlying all asymmetric synthesis therefore involve enantiomerically pure compounds to influence the stereochemical outcome of the reactions. In this review, the advances in asymmetric synthesis of some important classes of chiral organoselenium compounds were described.
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Cite this article as:
Zhu Chengjian and Huang Yijun, Asymmetric Synthesis of Chiral Organoselenium Compounds, Current Organic Chemistry 2006; 10 (15) . https://dx.doi.org/10.2174/138527206778521240
DOI https://dx.doi.org/10.2174/138527206778521240 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
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