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Letters in Organic Chemistry

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ISSN (Online): 1875-6255

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Research Article

Antioxidant Properties of Synthesis Nanometallic Pd-Ni@2- Mercaptoethanol as Effective Catalyst for Suzuki-Miyaura Reactions

Author(s): Khemais Said*, Ali Mesni and Ridha B. Salem

Volume 17, Issue 1, 2020

Page: [36 - 45] Pages: 10

DOI: 10.2174/1570178616666190319160151

Price: $65

Abstract

The palladium-catalyzed Suzuki coupling reaction is one of the most efficient strategies for constructing a carbon-carbon bond. In recent years, bimetallic catalysts have become candidates for the Suzuki coupling reaction. In this work, Pd-Ni@2-Mercaptoethanol nanoparticles were synthesized for the Suzuki-Miyaura cross-coupling of arylboronic acids with aryl bromides, in the N,Ndimethylformamide/ water mixture catalyzed by Pd-Ni: A simple and efficient reaction performed in a solvent, without a ligand, and in open air. We found that the Suzuki-Miyaura reactions are remarkably fast (5 min), with high yields and the products are highly pure. The Pd-Ni@2-Mercaptoetanol nanoparticles have a narrow size distribution with a mean crystallite size of 10 nm. Radical scavenging activities of the complexes have been evaluated by using DPPH, DMPD+ and ABTS+ assays. IC50 values (µg/ml) of the complexes and standards on DPPH, DMPD+ and ABTS+ respectively following the sequences.

Keywords: Nanoparticles, Suzuki C-C coupling, ROS scavenging activities, ultrasound, arylboronic acids, biaryls.

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