Novel Benzo-15-crown-5/C₆₀ Dyads with Different Chains: Synthesis and Complexation Properties

Title:Novel Benzo-15-crown-5/C₆₀ Dyads with Different Chains: Synthesis and Complexation Properties

Volume: 11 Issue: 1

Author(s): Biqiong Hong, Fafu Yang, Jinqi Ye, Hongyu Guo and Xiaoyun Yan

Affiliation:

Keywords: C₆₀, benzo-15-crown-5, chain, synthesis, complexation.

Abstract: Using benzo-15-crown-5 derivatives as starting materials, two novel benzo-15-crown-5/C₆₀ dyads with different linking chains were designed and synthesized in good yields by 1,3-dipolar cycloaddition of azomethine ylide generated in situ from aldehyde and sarcosine tied to C₆₀. It was found that their UV-Vis absorption spectra could be regulated hypsochromically by metal ions complexation. The long and soft linking chain was favorable for cooperate interaction of crown ether unit and C₆₀ unit.

Cite this article as:

Hong Biqiong, Yang Fafu, Ye Jinqi, Guo Hongyu and Yan Xiaoyun, Novel Benzo-15-crown-5/C₆₀ Dyads with Different Chains: Synthesis and Complexation Properties, Letters in Organic Chemistry 2014; 11 (1) . https://dx.doi.org/10.2174/157017861101140113155347