Abstract
A novel diepoxide containing paracyclophane was synthesized by peracid oxidation of a known paracyclophane diene. The resulting diepoxide was characterized. It was investigated as a potential monomer for a cyclophane containing polyether by cationic ring opening polymerization. None of the standard catalyst systems for such a polymerization were successful in producing polymer.
Keywords: Cationic polymerization, cyclophane, diepoxide, macrocycle, Dienes, literature, polymerization, Delta, x-frequency, Hofmann elimination.
Letters in Organic Chemistry
Title:Synthesis, Structure and Attempted Polymerization of a Diepoxide Macrocycle
Volume: 9 Issue: 8
Author(s): Paul Yarincik and Jeffrey H. Glans
Affiliation:
Keywords: Cationic polymerization, cyclophane, diepoxide, macrocycle, Dienes, literature, polymerization, Delta, x-frequency, Hofmann elimination.
Abstract: A novel diepoxide containing paracyclophane was synthesized by peracid oxidation of a known paracyclophane diene. The resulting diepoxide was characterized. It was investigated as a potential monomer for a cyclophane containing polyether by cationic ring opening polymerization. None of the standard catalyst systems for such a polymerization were successful in producing polymer.
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Cite this article as:
Yarincik Paul and H. Glans Jeffrey, Synthesis, Structure and Attempted Polymerization of a Diepoxide Macrocycle, Letters in Organic Chemistry 2012; 9 (8) . https://dx.doi.org/10.2174/157017812802850177
DOI https://dx.doi.org/10.2174/157017812802850177 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
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