An Efficient Microwave-Promoted Solvent-Free α-Phosphoryloxylation of Ketones

Title:An Efficient Microwave-Promoted Solvent-Free α-Phosphoryloxylation of Ketones

Volume: 9 Issue: 7

Author(s): Ye Pu, Yingguo Fang and Jie Yan

Affiliation:

Keywords: α-Phosphoryloxylation, (Diacetoxyiodo)benzene, ketol phosphate, ketone, microwave irradiation, synthesis, iodine, acetophenone, diphenyl, water

Abstract: An efficient solvent-free α-phosphoryloxylation of ketones under microwave irradiation is reported. When ketones reacted with phosphates and (diacetoxyiodo)benzene under microwave irradiation for short time, the α-phosphoryloxylaction of ketones was easily be carried out and the corresponding ketol phosphates were prepared in moderate to good yields.

Cite this article as:

Pu Ye, Fang Yingguo and Yan Jie, An Efficient Microwave-Promoted Solvent-Free α-Phosphoryloxylation of Ketones, Letters in Organic Chemistry 2012; 9 (7) . https://dx.doi.org/10.2174/157017812802139717