Advances in Organic Synthesis

Volume: 1

Activation of Organic Reactions by Perchlorates

Author(s): Suvarna S. Deshpande and Anil Kumar

Pp: 215-232 (18)

Doi: 10.2174/978160805197710501010215

* (Excluding Mailing and Handling)

Abstract

Perchlorates have been frequently employed to promote a variety of synthetic transformations under ambient conditions. For example, the LiClO4-diethyl ether solvent medium has proven to be a powerful substitute for external high pressure for Diels-Alder reactions and other organic reactions. In this chapter are discussed several such organic transformations where perchlorates have played highly significant role in promoting their rates and yields.

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