Generic placeholder image

Recent Innovations in Chemical Engineering


ISSN (Print): 2405-5204
ISSN (Online): 2405-5212

Research Article

Thermodynamics, Kinetics and Isotherms Studies for Sorption of Direct Dye onto the Pectinase Pre-treated Jute Yarn

Author(s): Ali Akbar Zolriasatein*

Volume 12 , Issue 2 , 2019

Page: [160 - 171] Pages: 12

DOI: 10.2174/2405520412666190618144005

Price: $65


Background & Objective: In this paper, jute yarns were bio-treated with pectinase enzyme. Then, the untreated and bio-treated yarns were dyed with Direct Yellow 24. The biotreated jute yarn showed higher dye sorption compared to that of untreated jute yarn.

Methods: The sorption isotherms were fitted with the Nernst, Freundlich, Langmuir, Temkin and BET models. At all temperatures studied, the experimental data were better described with the Freundlich model. Thermodynamic parameters such as a change in free energy (ΔG0), the enthalpy (ΔH0), and the entropy (ΔS0) were also evaluated. The values of ΔH0 and ΔG0 indicated that the sorption of direct dye onto jute yarn was a physical sorption process. Furthermore, the sorption process was exothermic and spontaneous.

Results: The results indicated that bio-treated jute yarn was more favorable (1/n < 1) for the sorption of direct dye as compared to that of untreated jute yarn (1/n > 1).

Conclusion: Among the kinetic models studied, it was found that the pseudo second-order kinetic model was the best model to describe the sorption process of Direct Yellow 24 onto the bio-treated and untreated jute yarns.

Keywords: Jute, pectinase enzyme, direct dye, adsorption isotherms, kinetics, thermodynamics.

Graphical Abstract
Cai Y, David S, Pailthorpe M. Dyeing of jute and jute/cotton blend fabrics with 2:1 pre-metallised dyes. Dyes Pigments 2000; 45(2): 161-8.
Shahidullah M, Islam RM, Alamgir SM, Uddin KM, Abdullah A. Improvement of light fastness properties of dyed jute fabrics through pretreatment. J Appl Sci (Faisalabad) 2007; 7(23): 3791-5.
Salam M. Study of color fastness properties onto bleached sulfunated jute-cotton blended fabrics with basic dyes. J Textile Apparel Technol Manag 2005; 4(4): 1-6.
Wang W, Cai Z, Yu J. Study on the chemical modification process of jute fiber. J Eng Fibers Fabrics 2008; 3(2): 1-11.
Vigneswaran C, Jayapriya J. Effect on physical characteristics of jute fibres with cellulase and specific mixed enzyme systems. J Textil Inst 2010; 101(6): 506-13.
Salam M, Sheik R, Farouique F. Improvement of color fastness properties onto bleached sulfonated jute with direct dyes. J Textile Apparel Technol Manag 2006; 5(3): 1-4.
Basu G, De S, Samanta A. Effect of bio-friendly conditioning agents on jute fiber spinning. Ind Crops Prod 2009; 29(2-3): 281-8.
Kundu A, Ghosh B, Chakrabarti S. Enhanced bleaching and softening of jute pretreated with polysaccharide degrading enzymes. Text Res J 1993; 63(8): 451-4.
Majumdar S, Kundu A, Dey S, Ghosh B. Enzymatic retting of jute ribbons. Int Biodeterior 1991; 27(3): 223-35.
Sever K, Sarikanat M, Seki Y, Erkan G, Erdoğan Ü, Erden S. Surface treatments of jute fabric: The influence of surface characteristics on jute fabrics and mechanical properties of jute/polyester composites. Ind Crops Prod 2012; 35(1): 22-30.
Sreenath H, Shah A, Yang V, Gharia M, Jeffries T. Enzymatic polishing of jute/cotton blended fabrics. J Ferment Bioeng 1996; 81(1): 18-20.
Pan N, Chattopadhyay S, Day A. Dyeing of biotreated jute fabric. J Nat Fibers 2007; 4(2): 67-76.
Salam M, Sheik R, Farouique F. Effect of salts on dying into jute with reactive, direct, basic and mordant dyes. J Textile Apparel Technol Manag 2009; 6(2): 1-6.
Samanta A, Agarwal P. Physico-chemical studies on dying of jute and cotton fabrics using jackfruit wood extract: Part II - Dying kinetics and thermodynamic studies. Indian J Fibre Text Res 2008; 33: 66-72.
Senthilkumaar S, Varadarajan PR, Porkodi K, Subbhuraam CV. Adsorption of methylene blue onto jute fiber carbon: Kinetics and equilibrium studies. J Colloid Interface Sci 2005; 284(1): 78-82.
[] [PMID: 15752787]
Porkodi K, Kumar VK. Equilibrium, kinetics and mechanism modeling and simulation of basic and acid dyes sorption onto jute fiber carbon: Eosin yellow, malachite green and crystal violet single component systems. J Hazard Mater 2007; 143(1-2): 311-27.
[] [PMID: 17069970]
Asadullah M, Asaduzzaman M, Kabir MS, Mostofa MG, Miyazawa T. Chemical and structural evaluation of activated carbon prepared from jute sticks for brilliant green dye removal from aqueous solution. J Hazard Mater 2010; 174(1-3): 437-43.
[] [PMID: 19815339]
Zolriasatein A, Yazdanshenas M, Khajavi R, Rashidi A. Effects of commercial laccase enzyme on appearance and light fastness of lingocellulosic jute yarn. Asian J Chem 2011; 23: 4677-80.
Zolriasatein A, Yazdanshenas M. Changes in composition, appearance, physical, and dyeing properties of jute yarn after bio-pretreatment with laccase, xylanase, cellulase, and pectinase enzymes. J Textil Inst 2013; 105(6): 609-19.
Zolriasatein A, Hajilari M. Effect of endo-1,4-β-xylanase enzyme on appearance and physical properties of jute yarn. Res J Pharm Biol Chem Sci 2015; 6(4): 862-8.
Limousin G, Gaudet J, Charlet L, Szenknect S, Barthès V, Krimissa M. Sorption isotherms: A review on physical bases, modeling and measurement. Appl Geochem 2007; 22(2): 249-75.
Demir H, Top A, Balköse D, Ulkü S. Dye adsorption behavior of luffa cylindrica fibers. J Hazard Mater 2008; 153(1-2): 389-94.
[] [PMID: 17919814]
Wu CH. Adsorption of reactive dye onto carbon nanotubes: Equilibrium, kinetics and thermodynamics. J Hazard Mater 2007; 144(1-2): 93-100.
[] [PMID: 17081687]
Özcan AS, Erdem B, Özcan A. Adsorption of acid blue 193 from aqueous solutions onto Na-bentonite and DTMA-bentonite. J Colloid Interface Sci 2004; 280(1): 44-54.
[] [PMID: 15476772]
Allen SJ, McKay G, Porter JF. Adsorption isotherm models for basic dye adsorption by peat in single and binary component systems. J Colloid Interface Sci 2004; 280(2): 322-33.
[] [PMID: 15533404]
Namasivayam C, Kavitha D. Removal of congo red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes Pigments 2002; 54(1): 47-58.
Kuo CY, Wu CH, Wu JY. Adsorption of direct dyes from aqueous solutions by carbon nanotubes: Determination of equilibrium, kinetics and thermodynamics parameters. J Colloid Interface Sci 2008; 327(2): 308-15.
[] [PMID: 18786679]
Vieira AP, Santana SA, Bezerra CW, et al. Kinetics and thermodynamics of textile dye adsorption from aqueous solutions using babassu coconut mesocarp. J Hazard Mater 2009; 166(2-3): 1272-8.
[] [PMID: 19150173]
Farizadeh K, Yazdanshenas M, Montazer M, Malek R, Rashidi A. Kinetic studies of adsorption of madder on wool using various models. Text Res J 2009; 80(9): 847-55.
Liu Y, Liu Y. Biosorption isotherms, kinetics and thermodynamics. Separ Purif Tech 2008; 61(3): 229-42.
Maarof HI, Hameed BH, Ahmad AL. Proceedings of the 4th Annual Seminar of National Science Fellowship Penang. Malaysia. December 20-21, 2004; 591-6.

Rights & Permissions Print Export Cite as
© 2022 Bentham Science Publishers | Privacy Policy