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Combinatorial Chemistry & High Throughput Screening

Editor-in-Chief

ISSN (Print): 1386-2073
ISSN (Online): 1875-5402

Application of Non-Covalently Solid-Phase Bound Catalysts

Author(s): F. Michalek, J. Horn, C. C. Tzschucke and W. Bannwarth

Volume 6, Issue 7, 2003

Page: [729 - 740] Pages: 12

DOI: 10.2174/138620703771981250

Price: $65

Abstract

Supported catalysts have become valuable tools for simplified product isolation and catalyst recycling. The common method is covalent attachment to a solid support. An alternative strategy is to immobilize catalysts by non-covalent bonding through hydrogen bridges, ionic, hydrophobic or fluorous interactions. Compared to covalent attachment, such non-covalent approaches increase the flexibility in the choice of the support-material, reaction conditions and work-up strategies. Numerous catalytic reactions employing one of these non-covalent fixation strategies have meanwhile appeared in the literature.

Keywords: supported catalysts, non-covalent immobilization, heterogeneous catalysis


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