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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Chirality of Hypervalent Chalcogenuranes

Author(s): Jozef Drabowicz, Jacek Chrzanowski, Dorota Krasowska and Adrian Zajac

Volume 20, Issue 2, 2016

Page: [146 - 154] Pages: 9

DOI: 10.2174/1385272819666150724233459

Price: $65

Abstract

This review presents synthetic procedures applied to the preparation of chiral (mainly optically active) hypervalent chalcogenuranes. The stereoisomerization mechanisms of hypervalent derivatives of sulfur, selenium and tellurium and their selected interconversions are also presented.

Keywords: Hypervalency, chirality, sulfurane, selenurane, tellurane, Berry pseudorotation, turnstile rotation.

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