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Current Organic Synthesis

Editor-in-Chief

ISSN (Print): 1570-1794
ISSN (Online): 1875-6271

Developments of Corey-Chaykovsky in Organic Reactions and Total Synthesis of Natural Products

Author(s): Majid M. Heravi, Shima Asadi, Niousha Nazari and Boshra Malekzadeh Lashkariani

Volume 13, Issue 3, 2016

Page: [308 - 333] Pages: 26

DOI: 10.2174/1570179412666150710182304

Price: $65

Abstract

The reactions of sulfur ylides with carbonyl, olefin or imine compounds named as the Corey- Chaykovsky, provide oxiranes, cyclopropane or aziridine, respectively. In this report, we try to introduce this important name reaction and highlight a comprehensive overview on the applications of this useful reaction in synthetic organic chemistry and total synthesis of natural products.

Keywords: Corey-Chaykovsky, epoxidation, dimethylsulfoxonium methylide, dimethylsulfonium methylide, organic and total synthesis.


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