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Current Inorganic Chemistry (Discontinued)

Editor-in-Chief

ISSN (Print): 1877-9441
ISSN (Online): 1877-945X

Formation of Ni(II) Oxime-Bridged Basket-Like Complexes and their Structural Aspects

Author(s): Malgorzata Holynska

Volume 5, Issue 1, 2015

Page: [64 - 70] Pages: 7

DOI: 10.2174/1877944105666150417231329

Price: $65

Abstract

Two new Ni(II) complexes with phenyl 2-pyridyl ketoxime ligand are reported, displaying unprecedented basket-like topologies of their complex cores. The compounds are studied by X-ray diffraction, EDX and IR spectroscopy, confirming uncommon coordination of a DMF ligand in one of them.The reaction system is described in detail and some of the products are analyzed by EDX/SEM, including EDX mapping analyses of the elemental distribution.

Keywords: Crystal structure, EDX, hydrogen bonding, IR, metal complex, nickel(II), oxime, perchlorate, SEM, synthesis.

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