Abstract
Due to their relevance in biological processes, molybdenum-catalyzed oxygen-transfer reactions have attracted considerable interest. In this context, some dioxomolybdenum(VI) complexes, with the cis-[MoO2]2+ core, that mimic oxotransferases, have been found to be efficient catalysts for several oxidation and reduction reactions in organic synthesis. More recently, the utility of these molybdenum( VI) complexes has been extended to other processes such as hydrosilylation reactions and, due to the amphoteric character of the Mo=O unit, to some Lewis acid-Lewis base conjugate catalyzed reactions.
Keywords: Molybdenum, catalysis, oxygen atom transfer, hydrosilylation, amphoteric catalysts
Call for Papers in Thematic Issues
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Organic synthesis is a fundamental discipline in chemistry, crucial for the creation of complex molecules with diverse applications in pharmaceuticals, materials science, and beyond. However, the process of designing efficient synthetic routes for target molecules remains challenging. Chemical graph theory, a branch of theoretical chemistry, offers powerful tools for understanding ...read more
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