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Letters in Organic Chemistry


ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Substituted Dienols from Palladium Catalyzed Coupling of Hydroaluminated Enynols with Aryl Iodides

Author(s): Kenneth E. Crook, Jin Nie and Mark E. Welker

Volume 5 , Issue 3 , 2008

Page: [158 - 164] Pages: 7

DOI: 10.2174/157017808783955790

Price: $65


Enynols were hydroaluminated and cross coupled with aryl iodides. Reduction of the yne portion of the enynol is a serious side reaction so reaction conditions to minimize reduction and maximize cross coupling were investigated in detail.

Keywords: Hydroalumination, cross coupling, enynols, ynols

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