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Current Organic Chemistry


ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Non-Deprotonating Methodologies for Organolithium Reagents Starting from Non-Halogenated Materials. Part 2: Transmetallation and Addition to Multiple Bonds

Author(s): David Guijarro, Isidro M. Pastor and Miguel Yus

Volume 15, Issue 14, 2011

Page: [2362 - 2389] Pages: 28

DOI: 10.2174/138527211796150589

Price: $65


The recent publications on the topic of the preparation of organolithium reagents by non-deprotonating methodologies and starting from non-halogenated substrates have been covered in the present revision. In this second part, transmetallation processes, mainly tin – lithium exchange, and addition to multiple bonds have been considered. Moreover, other procedures, such as carbon – carbon bond scission and the Shapiro reaction, have been included.

Keywords: Lithium, organolithiums, arene-catalysed lithiation, carbolithiation, tin/lithium exchange, transmetallation, reductive cleavage, aza-Wittig rearrangement, Organotin compounds, -aminoorganostannanes, Shapiro reaction, asymmetric cyclisation, Cyanopyridines, benzylic lithium carbanion, non-halogenated substrates

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