Abstract
The application of green solvents such as ionic liquids and water is currently being vigorously pursued because of attractive features such as the acceleration of a variety of reactions, their non-toxic nature, the possibility of dissolving a variety of reactants and recyclability in the case of ionic liquids, and cheapness in the case of water. The present review summarizes and critically discusses the data accumulated in recent years on the utilization of these solvents in the field of the synthesis of organophosphorus compounds. Ionic liquids and water were found to be especially suitable for P=O olefinations, synthesis of α- and β-aminophosphonates and some nucleophilic displacement reactions while in some cases they may change the reaction course observed in common organic solvents.
Keywords: ionic liquids, water, organophosphorus compounds, P=O olefinations, 'green' solvents, organic solvents
Current Organic Chemistry
Title: Ionic Liquids and Water as “Green” Solvents in Organophosphorus Synthesis
Volume: 14 Issue: 12
Author(s): I.L. Odinets and E.V. Matveeva
Affiliation:
Keywords: ionic liquids, water, organophosphorus compounds, P=O olefinations, 'green' solvents, organic solvents
Abstract: The application of green solvents such as ionic liquids and water is currently being vigorously pursued because of attractive features such as the acceleration of a variety of reactions, their non-toxic nature, the possibility of dissolving a variety of reactants and recyclability in the case of ionic liquids, and cheapness in the case of water. The present review summarizes and critically discusses the data accumulated in recent years on the utilization of these solvents in the field of the synthesis of organophosphorus compounds. Ionic liquids and water were found to be especially suitable for P=O olefinations, synthesis of α- and β-aminophosphonates and some nucleophilic displacement reactions while in some cases they may change the reaction course observed in common organic solvents.
Export Options
About this article
Cite this article as:
Odinets I.L. and Matveeva E.V., Ionic Liquids and Water as “Green” Solvents in Organophosphorus Synthesis, Current Organic Chemistry 2010; 14 (12) . https://dx.doi.org/10.2174/138527210791330486
DOI https://dx.doi.org/10.2174/138527210791330486 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
Call for Papers in Thematic Issues
Advances of Heterocyclic Chemistry with Pesticide Activity
Global food safety and security will continue to be a global concern for the next 50 years and beyond. Plant diseases have had a significant impact on food safety and security throughout the entire food chain, from primary production to consumption. While conventional chemical pesticides have been traditionally used for ...read more
Calculation design of covalent/metal organic framework based catalysts
This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
Related Journals
- Author Guidelines
- Graphical Abstracts
- Fabricating and Stating False Information
- Research Misconduct
- Post Publication Discussions and Corrections
- Publishing Ethics and Rectitude
- Increase Visibility of Your Article
- Archiving Policies
- Peer Review Workflow
- Order Your Article Before Print
- Promote Your Article
- Manuscript Transfer Facility
- Editorial Policies
- Allegations from Whistleblowers
- Announcements
Related Articles
-
Validation of the Neuroinflammation Cycle as a Drug Discovery Target Using Integrative Chemical Biology and Lead Compound Development with an Alzheimers Disease-Related Mouse Model
Current Alzheimer Research Systemic Approach to the Study of Complex Bone Disorders at the Whole- Genome Level
Current Genomics Potential Implications of Black Seed and its Principal Constituent Thymoquinone in the Treatment of COVID-19 Patients
Current Pharmaceutical Biotechnology Recent Advances in Cartilage Regenerative Technologies
Recent Patents on Biomedical Engineering (Discontinued) Targeting Hypoxia for Sensitization of Tumors to Radio- and Chemotherapy
Current Cancer Drug Targets Impact of Early Life Stress on the Pathogenesis of Mental Disorders: Relation to Brain Oxidative Stress
Current Pharmaceutical Design HLA Class I Expression, Tumor Escape and Cancer Progression
Current Cancer Therapy Reviews The Link Between CD6 and Autoimmunity: Genetic and Cellular Associations
Current Drug Targets Relevance of Nutritional Antioxidants in Metabolic Syndrome, Ageing and Cancer: Potential for Therapeutic Targeting
Infectious Disorders - Drug Targets AZT: An Old Drug with New Perspectives
Current Clinical Pharmacology Chemotherapy-Induced Modifications to Gastrointestinal Microflora: Evidence and Implications of Change
Current Drug Metabolism Pyridine Moiety: An Insight into Recent Advances in the Treatment of Cancer
Mini-Reviews in Medicinal Chemistry Influence of Two Cyclodextrin HP-derivatives on Retention and Migration Distance of Some Isomers in High- Performance Thin-Layer Chromatography and Pressurized Planar Electrochromatography Systems with Non-polar Adsorbents
Current Analytical Chemistry Subject Index to Volume 2
Current Medicinal Chemistry - Anti-Inflammatory & Anti-Allergy Agents K114 Inhibits A-beta Aggregation and Inflammation In Vitro and In Vivo in AD/Tg Mice
Current Alzheimer Research The Immunomodulatory Potential of Selected Bioactive Plant-Based Compounds in Breast Cancer: A Review
Anti-Cancer Agents in Medicinal Chemistry The Multiple Layers of Signaling Selectivity at Protease-Activated Receptors
Current Pharmaceutical Design Peroxisome Proliferator-Activated Receptor-γ (PPAR-γ) Agonists on Glycemic Control, Lipid Profile and Cardiovascular Risk
Current Molecular Pharmacology A Systematic Review of Genes Involved in the Inverse Resistance Relationship Between Cisplatin and Paclitaxel Chemotherapy: Role of BRCA1
Current Cancer Drug Targets Terpenoids and Glycolipids from Euphorbiaceae
Mini-Reviews in Medicinal Chemistry