Synthesis of Mycinose from 1,2:5,6-Di-O-Isopropylidene-α-D-glucofuranose

Author(s): Kai Bao, Hao Gao, Zhibin Zhu, Jinhong Wang, Guoning Zhang, Jun Sun, Weige Zhang, Xinsheng Yao.

Journal Name: Letters in Organic Chemistry

Volume 8 , Issue 8 , 2011

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Abstract:

A facile synthesis of mycinose from commercially available 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose was developed. A selective and direct reductive debromination of α-hydroxy bromides in a simple NaBH4/EtOH/H2O system was found.

Keywords: 1,2:5,6-Di-O-Isopropylidene-α-D-glucofuranose, debromination, mycinose, synthesis, glucofuranose, stoichiometry, hydroxyl group, Microwave assisted deprotection, spectroscopy, sodium borohydride

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Article Details

VOLUME: 8
ISSUE: 8
Year: 2011
Page: [592 - 595]
Pages: 4
DOI: 10.2174/157017811797249290
Price: $58

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