Stereoselective Chlorination of New Type Baylis-Hillman Adducts by bis(Trichloromethyl)carbonate with the Aid of Catalytic Amount of Triphenylphosphine Oxide

Author(s): Weihui Zhong, Lingjuan Hong, Yemin Zheng.

Journal Name: Letters in Organic Chemistry

Volume 7 , Issue 3 , 2010

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Abstract:

The chlorination of the new type Baylis-Hillman adducts by bis(trichloromethyl)carbonate (BTC) with the aid of catalytic amount of triphenylphosphine oxide (Ph3PO) was achieved with high yields and high stereoselectivities. A plausible mechanism is presented.

Keywords: New type Baylis-Hillman adducts, chlorination, triphenylphosphine oxide, bis(trichloromethyl)carbonate, stereoselectivity

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Article Details

VOLUME: 7
ISSUE: 3
Year: 2010
Page: [229 - 234]
Pages: 6
DOI: 10.2174/157017810791112469
Price: $65

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