Reaction of Atomic Carbon with Isomeric Cresols (Supplementary Material)

Author(s): Ilkay Sokmen, Abdulilah Ece, Bulent Duz, Fatma Sevin.

Journal Name: Letters in Organic Chemistry

Volume 6 , Issue 8 , 2009

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Abstract:

Reaction of atomic carbon with isomeric cresols generates methyltropones and xylenols. Methyltropone to xylenol ratio was found to be highest for m-cresol and lowest for p-cresol. Stability of singlet carbenes produced after insertion of atomic carbon into C-H bonds of cresols plays an important role in the observed ratios.

Keywords: Carbon arc, carbene, methyltropone, xylenol

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Article Details

VOLUME: 6
ISSUE: 8
Year: 2009
Page: [650 - 653]
Pages: 4
DOI: 10.2174/157017809790442907
Price: $58