The Synthesis, Reactivity and NMR Investigation on 15N-Thiophosphoramidates (Supplementary Material)

Author(s): Tomasz Ruman, Karolina Dlugopolska, Agata Jurkiewicz, Dagmara Kramarz, Tomasz Fraczyk, Andrzej Les, Wojciech Rode.

Journal Name: Letters in Organic Chemistry

Volume 6 , Issue 8 , 2009

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Abstract:

Novel 15N-isotope enriched potassium and diammonium thiophosphoramidates were synthesized and their spectroscopic properties, along with reactivity towards several compounds, including histidine, thymidine, glucose and 2- deoxyribose are presented. The application of quantum mechanical DFT calculations for estimation of 31P NMR chemical shifts for several thiophosphoramidate ions and its derivatives are also discussed.

Keywords: NMR, thiophosphate, tiophosphoramidate, thiophosphorylation

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Article Details

VOLUME: 6
ISSUE: 8
Year: 2009
Page: [642 - 647]
Pages: 6
DOI: 10.2174/157017809790442943
Price: $58

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