Chiral Sulfur Ligands for Catalytic Asymmetric Synthesis

Author(s): Kunio Hiroi , Takanori Sone .

Journal Name: Current Organic Synthesis

Volume 5 , Issue 4 , 2008

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Abstract:

Chiral sulfur ligands which have been developed quite recently bu us are reviewed. Several types of chiral sulfur ligands, which involve a chiral sulfoxide group as a sole chiral source, and other coordinating elements such as phosphine, nitrogen, oxygen, sulfur, and so on, have been developed. A role of the chiral sulfoxide functions as ligands in metal-catalyzed asymmetric synthesis has been revealed by the X-ray crystallographic analysis of the intermediary metal complexes.

Keywords: Chiral Sulfur Ligands, Catalytic Asymmetric Synthesis, chiral source, phosphine, metal-catalyzed asymmetric synthesis, X-ray crystallographic, metal complexes

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Article Details

VOLUME: 5
ISSUE: 4
Year: 2008
Page: [305 - 320]
Pages: 16
DOI: 10.2174/157017908786241608
Price: $58

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