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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Easy Electrochemical Synthesis of 2-amino-4-aryl-3-cyano-5-ethoxycarbonyl- 6-methyl-4H-pyrans in the Absence of Supporting Electrolyte

Author(s): Giovanni Sotgiu

Volume 5, Issue 7, 2008

Page: [555 - 558] Pages: 4

DOI: 10.2174/157017808785982202

Price: $65

Abstract

An easy electrochemical synthesis of 2-amino-4-aryl-3-cyano-5-ethoxycarbonyl-6-methyl-4H-pyrans has been set up, by galvanostatic electrolysis of a mixture of arylidenemalononitrile and ethyl acetoacetate in the absence of supporting electrolyte. Very high yields are obtained by a particularly simple procedure.

Keywords: Arylidenemalononitriles, electrochemistry, ethyl acetoacetate, green chemistry, 4H-pyrans


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