Exploration of Molybdenum(V) Chloride as a Lewis Acid Catalyst in Various C-C Bond Formation Reactions

Author(s): Chada R. Reddy, Nagavaram N. Rao, Ambadi Sudhakar.

Journal Name: Letters in Organic Chemistry

Volume 5 , Issue 6 , 2008

Become EABM
Become Reviewer

Abstract:

The catalytic activity of Molybdenum(V) chloride as a Lewis acid in carbon-carbon bond formation reactions has been described. The reactions of various substrates viz. aldehydes, benzyl alcohols, glucals and aminals with carbon nucleophiles were studied in the presence of MoCl5 as a catalyst. Progress of all the reactions proceeded smoothly to furnish the corresponding products in good yields.

Keywords: Molybdenum(V) chloride, carbon-carbon bond formation, allylation, Lewis acid, glycosylation

Rights & PermissionsPrintExport Cite as

Article Details

VOLUME: 5
ISSUE: 6
Year: 2008
Page: [473 - 477]
Pages: 5
DOI: 10.2174/157017808785740507
Price: $65

Article Metrics

PDF: 7