A Convenient Access to the Piperidine Ring by Cyclization of Allylsilyl Substituted N- cyliminium and Iminium Ions: Application to the Synthesis of Piperidine Alkaloids.

Author(s): R. Remuson, Y. Gelas-Mialhe.

Journal Name: Mini-Reviews in Organic Chemistry

Volume 5 , Issue 3 , 2008

Abstract:

This review relates a new access to the piperidine ring by intramolecular cyclization of acyl iminium and iminium ions substituted by an allylsilyl side chain as an internal Π-nucleophile. This methodology was applied to the synthesis of piperidine alkaloids

Keywords: Piperidine, iminium ions, N-acyliminium ions, indolizidine, quinolizidine

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Article Details

VOLUME: 5
ISSUE: 3
Year: 2008
Page: [193 - 208]
Pages: 16
DOI: 10.2174/157019308785161701
Price: $58

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