PolyHIPEs as Novel Media for Conventional Free Radical Chemistry

Author(s): Shengmiao Zhang, Jianding Chen, Victoria T. Perchyonok.

Journal Name: Letters in Organic Chemistry

Volume 5 , Issue 4 , 2008

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Abstract:

The novel materials, polyHIPEs with incorporated tetrasubstituted ammonium cationic surfactant (CTAB) have been applied to a broad range of radical precursors in various free radical transformations in organic and aqueous media. The advantage of this reagent/ solid phase surfactant combination lies in its affordability, miniscule toxicity, avoidance of highly toxic “tin based hydrogen donors” under green reaction conditions.

Keywords: Free Radicals, PolyHIPEs as reaction media, synthesis, green chemistry

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Article Details

VOLUME: 5
ISSUE: 4
Year: 2008
Page: [304 - 307]
Pages: 4
DOI: 10.2174/157017808784049443
Price: $58