Tris(2-Hydroxyphenyl)Methanes: Ligand with High Affinity Toward a Chloride Anion

Author(s): Tatsunori Sato, Shintaro Higuchi, Kazuaki Ito.

Journal Name: Letters in Organic Chemistry

Volume 4 , Issue 8 , 2007

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Abstract:

Tris(2-hydroxyphenyl)methane derivatives (1) displayed excellent selectivity for chloride (Cl-), in comparison with bromide (Br-), iodide (I-) and nitrate (NO3 -) ions. This selectivity is attributed to the fit size and shape of chloride, which favor the formation of a stable host-guest complex through the multiple intermolecular hydrogen bonds between 1 and the chloride anion.

Keywords: Tris(2-hydroxyphenyl)methane, anion receptor, chloride anion selectivity, hydroxy group, multiple hydrogen bonding

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Article Details

VOLUME: 4
ISSUE: 8
Year: 2007
Page: [595 - 600]
Pages: 6
DOI: 10.2174/157017807782795574
Price: $58

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