Vanadium-Substituted Keggin Type Heteropolyacid are Used for the Selective Oxidation of Sulfides to Sulfoxides and Sulfones Using Hydrogen Peroxide

Author(s): Gustavo P. Romanelli, Daniel O. Bennardi, Valeria Palermo, Patricia G. Vazquez, Pietro Tundo.

Journal Name: Letters in Organic Chemistry

Volume 4 , Issue 8 , 2007

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Abstract:

Various types of aromatic and aliphatic sulfides are selectively oxidized to sulfoxides and sulfones with good to excellent yields using H2O2 35% p/V in the presence of catalytic amounts of Keggin heteropolyacid (H5PMo11Al0.5V0.5O40) using acetonitrile as solvent.

Keywords: Sulfides, sulfoxides, sulfones, hydrogen peroxide, keggin heteropolyacid, oxidation

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Article Details

VOLUME: 4
ISSUE: 8
Year: 2007
Page: [544 - 549]
Pages: 6
DOI: 10.2174/157017807782795592
Price: $58

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