Synthesis of 8,16-Ethanoretinals and Their Interactions with Apoprotein of Phoborhodopsin from Natronobacterium pharaonis

Author(s): Akimori Wada, Yoshimi Takakura, Kenta Yamazaki, Tetsuo Takahashi, Masayoshi Ito.

Journal Name: Letters in Organic Chemistry

Volume 1 , Issue 1 , 2004

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Abstract:

Several 8,16-Ethanoretinals 3 were synthesized from cyclohexanones. From the binding experiments of these analogs with apoprotein of phoborhodopsin, it was found that retinal was incorporated as 6s-trans conformation in the protein and the fine structure in absorption spectra of pigments were dependent on the coplanarity of the conjugated polyene structure in the chromophore.

Keywords: ethanoretinal, retinal analog, phoborhodopsin, chromophore, s-trans conformation

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Article Details

VOLUME: 1
ISSUE: 1
Year: 2004
Page: [59 - 62]
Pages: 4
DOI: 10.2174/1570178043488789

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