From the MARDi Cascade to the Stereoselective Construction of Functionalized Bicyclo[5.4.0]undecene Skeletons Occurring in Natural Compounds

Author(s): M.- H. Filippini, J. Rodriguez.

Journal Name: Letters in Organic Chemistry

Volume 1 , Issue 1 , 2004

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Abstract:

The stereoselective construction of functionalized bicyclo[5.4.0]undecene systems, found in many natural sesquiterpenes such as in the widdrane, guadalupane, and recently isolated guanacastepene families, is achieved by selective chemical transformations of a functionalized cycloheptanol arising from the MARDi cascade.

Keywords: mardi cascade, seven-membered rings, bicyclo[5.4.0]undecenes

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Article Details

VOLUME: 1
ISSUE: 1
Year: 2004
Page: [53 - 54]
Pages: 2
DOI: 10.2174/1570178043488716

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