1-Phenylethenyl phosphate derivatives of the monoester type were synthesized via the Perkow reaction. Among them, 2-(2,4-difluorophenyl)ethenyl phosphate was found to be obtained as a pure salt. It turned out that this compound and 2-phenylethenyl phosphate can transfer their phosphoryl groups to AMP in pyridine at elevated temperatures to give ADP.
Keywords: enol phosphate, phosphoryl transfer, phosphorylation, perkow reaction
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