Palladium or Iridium-Catalyzed Allylic Substitution of Guanidines having Electron-Withdrawing Substituents

Author(s): Hideto Miyabe, Akira Matsumura, Kazumasa Yoshida, Masashige Yamauchi, Yoshiji Takemoto.

Journal Name: Letters in Organic Chemistry

Volume 1 , Issue 2 , 2004

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Abstract:

As a new direct functionalization of guanidines, the N-allylic substitution of guanidines was studied. The nitrogen atom of guanidine derivatives having two Nelectron- withdrawing substituents acted as a reactive nucleophile in the allylic substitution.

Keywords: guanidine, palladium, iridium, catalytic reaction, allylation, allylic substitution

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Article Details

VOLUME: 1
ISSUE: 2
Year: 2004
Page: [119 - 121]
Pages: 3
DOI: 10.2174/1570178043488464
Price: $58

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