Imino-Ketenimines on an Ortho-Benzylic Scaffold. Nitrogen to Carbon [1,3] Shift of an Ortho-Functionalized Benzyl Group

Author(s): Mateo Alajarin, Angel Vidal, Fulgencio Tovar.

Journal Name: Letters in Organic Chemistry

Volume 1 , Issue 4 , 2004

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Abstract:

Thermolysis of C,C-disubstituted N-(2-benzylideneamino)benzyl ketenimines in solution provided 2,2-disubstituted 3-(2-benzylideneamino)phenylpropionitriles by [1,3] migration of the substituted benzyl group from nitrogen to carbon in the ketenimine fragment.

Keywords: imine, ketenimine, nitrile

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Article Details

VOLUME: 1
ISSUE: 4
Year: 2004
Page: [340 - 342]
Pages: 3
DOI: 10.2174/1570178043400398
Price: $58

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