Strategies of Synthetic Methodologies for Constructing β-Mannosidic Linkage

Author(s): E. S. H. El Ashry, N. Rashed, E. S. I. Ibrahim.

Journal Name: Current Organic Synthesis

Volume 2 , Issue 2 , 2005

Become EABM
Become Reviewer

Abstract:

The various synthetic methodologies for constructing the β-mannosidic bonds have been reviewed. Different strategies are covered such as inter and intramolecular glycosidation methods as well as epimerization of β-glucosides, reductive cleavage of anomeric orthoesters, radical anomeric inversion, enzymatic synthesis and mannosides from non-carbohydrate.

Keywords: glycosyl acceptors, mannosyl donor, aglycon delivery, epimerization, b-mannopyranosides, stereoselective mannosidation, 1,2-cis-mannosides, benzylsulfonyl

Rights & PermissionsPrintExport Cite as


Article Details

VOLUME: 2
ISSUE: 2
Year: 2005
Page: [175 - 213]
Pages: 39
DOI: 10.2174/1570179053545378
Price: $58

Article Metrics

PDF: 4