Solvothermal In Situ Ligand Synthesis, Crystal Structure and Fluorescent Properties of a New Heterocyclic Compound 1, 1 - Bis{3-(Pyridin-2-yl)HImidazo[ 1, 5-a]Pyridine}

Author(s): Cai-Ming Liu, Hong-Yun Gao, De-Qing Zhang, Dao-Ben Zhu.

Journal Name: Letters in Organic Chemistry

Volume 2 , Issue 8 , 2005

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Abstract:

Solvothermal in situ ligand reaction of bis(2-pyridinylmethyl)amine (bpa) in the presence of Fe(ClO4)2 × 6H2O and NaN3 yielded the crystalline fluorescent organic heterocyclic compound 1, 1-bis{3- (pyridin-2-yl)H-imidazo[1, 5-a]pyridine} 1 and the byproduct Fe(bpa)2(ClO4)2 2. Compound 1 is the first example of imidazo[1, 5-a]pyridine compound synthesized by in situ reaction under solvothermal conditions.

Keywords: Solvothermal synthesis, heterocyclic compound, imidazo[1, 5-a]pyridine compound, iron(II) complex, crystal structure, fluorescent property

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Article Details

VOLUME: 2
ISSUE: 8
Year: 2005
Page: [712 - 717]
Pages: 6
DOI: 10.2174/157017805774717427
Price: $65

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