Synthesis of Various Terphenyl Derivatives; Study of a New Amine Receptor with a Terphenyl Structure

Title: Synthesis of Various Terphenyl Derivatives; Study of a New Amine Receptor with a Terphenyl Structure

Volume: 2 Issue: 2

Author(s): Patricia Le Nahenec-Martel, Stephane Leleu, Francis Marsais, Cyril Papamicael, Vincent Levacher and Georges Dupas

Affiliation:

Keywords: molecular recognition, binding constants, terphenyl, amidines, amine receptor

Abstract: The synthesis of functionalized terphenyl derivatives was achieved starting from readily available 1,3-dichloro-2-iodobenzene. Among the prepared compounds, a molecule able to bind with benzylamine is described. This new host consist in a terphenyl structure possessing two side arms with aminomethylpyridines moieties. An interesting association constant with benzylamine and an unexpected 2/1 (host/guest) complex have been determined by using 1H NMR dilution experiments.

Cite this article as:

Nahenec-Martel Le Patricia, Leleu Stephane, Marsais Francis, Papamicael Cyril, Levacher Vincent and Dupas Georges, Synthesis of Various Terphenyl Derivatives; Study of a New Amine Receptor with a Terphenyl Structure, Letters in Organic Chemistry 2005; 2 (2) . https://dx.doi.org/10.2174/1570178053202955