Use of Alkoxyallene Oxide and Titanium Tetraiodide/Titanium Tetraisopropoxide for the Conjugate Addition Reaction of Alkoxyacetone Enolate

Author(s): M. Shimizu, S. Itohara.

Journal Name: Letters in Organic Chemistry

Volume 2 , Issue 7 , 2005

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Abstract:

An enolate synthon of alkoxyacetone was regioselectively generated using alkoxyallene oxide and titanium tetraiodide/titanium tetraisopropoxide, and the subsequent conjugate addition reaction with enones gave 4-alkoxy-1,5-diketones in good yields.

Keywords: alkoxyacetone, alkoxyallene oxide, titanium tetraiodide, conjugate addition

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Article Details

VOLUME: 2
ISSUE: 7
Year: 2005
Page: [648 - 651]
Pages: 4
DOI: 10.2174/157017805774296902
Price: $65

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