An Efficient and Facile Synthesis of Hexanitrohexaazaisowurtzitane (HNIW)

Author(s): Hua Qian, Zhi-Wen Ye, Chun-Xu Lv.

Journal Name: Letters in Organic Chemistry

Volume 4 , Issue 7 , 2007

Abstract:

New process to synthesize hexanitrohexaazaisowurtzitane (HNIW) using ultrasounds in ionic liquid (IL) was developed. Effects of various parameters were investigated to optimize the synthesis conditions. Meanwhile, the mechanism of reaction was also discussed. It was observed that ultrasonically promoted reaction of tetraacetyldibenzylhexaazaisowurtzitane (TADBIW) to HNIW has exhibited significant enhancement in yield at ambient condition.

Keywords: HNIW (hexanitrohexaazaisowurtzitane), TADBIW (tetraacetyldibenzylhexaazaisowurtzitane), ultrasounds, IL (ionic liquid), nitration, synthesis

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Article Details

VOLUME: 4
ISSUE: 7
Year: 2007
Page: [482 - 485]
Pages: 4
DOI: 10.2174/157017807782006353
Price: $58

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