Specificity in Crystal Engineering: Polymerisation and Dimerisation Motif Design in Pyridine System

Author(s): Shyamaprosad Goswami, Swapan Dey, Subrata Jana.

Journal Name: Letters in Organic Chemistry

Volume 4 , Issue 6 , 2007

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Abstract:

2-Amino-6-hydroxymethylpyridine (1) and 2-pivaloylamino-6-hydroxymethylpyridine (2) are important hydrogen bonding synthons as they are the very useful substrates which can be used for the synthesis of designed receptors in the field of molecular recognition [1] and supramolecular chemistry [2]. Here we report the compounds 1 and 2 as simple designers to create polymeric supramolecular three-dimensional assembly and self-complementary dimer respectively in solid-state crystal engineering.

Keywords: Hydrogen bonding synthons, supramolecular assembly, dimerisation and polymerization

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Article Details

VOLUME: 4
ISSUE: 6
Year: 2007
Page: [448 - 451]
Pages: 4
DOI: 10.2174/157017807781467669
Price: $65

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