Asymmetric Allylation of Aldehydes and Ketones Using Chiral Pyridine Bis(diphenyloxazoline)-Indium Complexes

Author(s): Wei-Yi Chen, Xin-Sheng Li.

Journal Name: Letters in Organic Chemistry

Volume 4 , Issue 6 , 2007

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Abstract:

Indium complexes of chiral pyridine bis(diphenyloxazoline)-type ligands have been investigated as catalysts for the asymmetric allylation of aldehydes and ketones. Promoted by these chiral catalysts, allyltributylstannane reacted with aldehydes and ketones to afford the corresponding optically active homoallylic alcohols smoothly.

Keywords: Asymmetric allylation, aldehyde, ketone, indium, chiral pybox

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Article Details

VOLUME: 4
ISSUE: 6
Year: 2007
Page: [398 - 403]
Pages: 6
DOI: 10.2174/157017807781467605
Price: $65

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