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Mini-Reviews in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-193X
ISSN (Online): 1875-6298

Electron-Transfer Processes Mediated by Alkalides: A Critical Approach

Author(s): Zbigniew Grobelny, Andrzej Stolarzewicz, Andrzej Swinarew, Marcin Szczepanski and Adalbert Maercker

Volume 4, Issue 3, 2007

Page: [254 - 267] Pages: 14

DOI: 10.2174/157019307781369913

Price: $65

Abstract

The objectives of this review are mainly reactions of alkalides with various classes of organic compounds. Mechanisms of these processes are discussed taking into account our present stage of knowledge. A new method for the preparation of crystalline nanomaterials via homogeneous reduction of transition and post-transition metal salts is also presented.

Keywords: Alkalides, potassium anions, two-electron-transfer, reduction, vinyl compounds, ethers, esters

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