Palladium-Catalyzed Cyanation of Aryl Bromides with Potassium Hexacyanoferrate (II)

Author(s): Yi-nan Cheng, Zheng Duan, Ting Li, Yangjie Wu.

Journal Name: Letters in Organic Chemistry

Volume 4 , Issue 5 , 2007

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Abstract:

Simple and efficient cyclopalladated ferrocenylimine/Cu and cyclopalladated ferrocenylimine catalyzed cyanation of aryl bromides with K4[Fe(CN)6] 3H2O were described. These procedures are applicable to both activated and deactivated aryl bromides. The corresponding benzonitriles were formed in good to excellent yields.

Keywords: Palladium, copper, cyanation, catalyst, aryl bromide

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Article Details

VOLUME: 4
ISSUE: 5
Year: 2007
Page: [352 - 356]
Pages: 5
DOI: 10.2174/157017807781212111
Price: $58

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