Hexamethylenetetramine-Ionic Liquids Catalyzed Baylis-Hillman Reactions

Author(s): Rodrigo O.M. A. de Souza, Pedro H. Fregadolli, Karen M. Goncalves, Lucia C. Sequeira, Vera L.P. Pereira, Lucio C. Filho, Pierre M. Esteves, Mario L.A.A. Vasconcello, Octavio A.C. Antunes.

Journal Name: Letters in Organic Chemistry

Volume 3 , Issue 12 , 2006

Abstract:

In the present paper it is described the use of hexamethylenetetramine combined to the use of bmim+ type ionic liquids as cheap, environmentally friendly and efficient catalytic systems for Baylis- Hillman reactions between aromatic aldehydes and acrylonitrile or methyl acrylate. The Baylis-Hillman adducts were obtained in moderate to good yields (50-85%), in short reaction times. The ionic liquids can be recycled.

Keywords: BmimPF6, bmimBF4, hexamethylenetetramine, non innocent, catalysis, green chemistry

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Article Details

VOLUME: 3
ISSUE: 12
Year: 2006
Page: [936 - 939]
Pages: 4
DOI: 10.2174/157017806779467942
Price: $58

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