Preparation of Heterocycles by Microwave-Induced Retro Diels-Alder Reaction

Author(s): Ferenc Miklos, Geza Stajer, Ferenc Fulop.

Journal Name: Letters in Organic Chemistry

Volume 3 , Issue 12 , 2006

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Abstract:

Pyrimidinone, thioxopyrimidinone, pyrimido[2,1-a]phthalazinone and [1,3]oxazino[2,3-a] isoindolone were obtained by means of microwave-assisted [4+2] cycloreversion. The microwave heating of the parent norbornene or oxanorbornene fused compounds in a solvent with a medium or large loss factor generates retro Diels-Alder products in excellent yield and high purity.

Keywords: Microwave, retro Diels-Alder reaction, N,N-, O,N-heterocycles

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Article Details

VOLUME: 3
ISSUE: 12
Year: 2006
Page: [915 - 916]
Pages: 2
DOI: 10.2174/157017806779468086
Price: $65

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