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Letters in Organic Chemistry

Editor-in-Chief

ISSN (Print): 1570-1786
ISSN (Online): 1875-6255

Indium-Mediated Allylation of α, α-Dichloroketones: The Synthesis of 1,1-Dichloro-2-organyl-pent-4-en-2-ols

Author(s): Clovis Peppe, Jose A. Nobrega, Lia D. Drehmer and Marcos A. P. Martins

Volume 3, Issue 8, 2006

Page: [597 - 599] Pages: 3

DOI: 10.2174/157017806778559437

Price: $65

Abstract

The allylindium reagents obtained from metallic indium and allyl bromides, in THF, couple chemioselectively to the carbonyl group of α,α- dichloroketones to afford 1,1-dichloro-2-organyl-pent-4-en- 2-ols in good to excellent yields.

Keywords: Indium, allylindium, allylation, dichloroketones


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