Indium-Mediated Allylation of α, α-Dichloroketones: The Synthesis of 1,1-Dichloro-2-organyl-pent-4-en-2-ols

Author(s): Clovis Peppe , Jose A. Nobrega , Lia D. Drehmer , Marcos A. P. Martins .

Journal Name: Letters in Organic Chemistry

Volume 3 , Issue 8 , 2006

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Abstract:

The allylindium reagents obtained from metallic indium and allyl bromides, in THF, couple chemioselectively to the carbonyl group of α,α- dichloroketones to afford 1,1-dichloro-2-organyl-pent-4-en- 2-ols in good to excellent yields.

Keywords: Indium, allylindium, allylation, dichloroketones

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Article Details

VOLUME: 3
ISSUE: 8
Year: 2006
Page: [597 - 599]
Pages: 3
DOI: 10.2174/157017806778559437
Price: $58

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