Hydrogen Bonding Molecular Recognition of Diphenols by a Novel 1,3- Alternate Calix[4]arene Receptor Bearing Two Dipyridyl Moieties

Author(s): Salvatore Gentile, Fabio G. Gulino, Domenico Sciotto, Carmelo Sgarlata.

Journal Name: Letters in Organic Chemistry

Volume 3 , Issue 1 , 2006

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Abstract:

The molecular recognition properties of a novel calix[4]arene receptor fixed in a 1,3-alternate conformation bearing two dipyridyl moieties towards organic molecules containing hydroxylic (phenolic or alcoholic) or amino functionalities have been investigated by 1H NMR spectroscopy in CDCl3. The novel receptor selectively recognizes by hydrogen bonding only molecules having two OH phenolic groups.

Keywords: Calixarenes, Molecular recognition, Hydrogen bonding, Diphenols

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Article Details

VOLUME: 3
ISSUE: 1
Year: 2006
Page: [48 - 53]
Pages: 6
DOI: 10.2174/157017806774964396

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