Palladium-Catalyzed Heterofunctionalization of C-H, C=C and C≡ C Bonds

Author(s): Luis A. Adrio , King Kuok (Mimi) Hii .

Journal Name: Current Organic Chemistry

Volume 15 , Issue 18 , 2011

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Abstract:

The heterofunctionalisation of C-H, C=C and C≡C bonds is an important type of transformation that converts readily accessible precursors to valuable intermediates in organic synthesis, particularly when the heteroatom = N or O. The progress in this area of homogeneous catalysis by palladium is described in the current review, covering the period between 2005-early 2010. Asymmetric reactions remain a key challenge in this area, which is highlighted.

Keywords: Palladium, homogeneous catalysis, C-H activation, C-C bond formation, C-X bond formation, catalytic cycles, Hydroamination, allylic electrophiles, Oxidative Amination Reactions, cyclooctadiene (COD), Diamination of Alkenes, Bronsted basic DIPEA, diastereoselectivity, Dioxygenation, Aminoacetoxylation, Diamination of, hydroquinone (HQ), chiral palladium(, aza-Michael reactions

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Article Details

VOLUME: 15
ISSUE: 18
Year: 2011
Page: [3337 - 3361]
Pages: 25
DOI: 10.2174/138527211797248003
Price: $58

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