Abstract
The concept of π-acid catalysis has emerged as a powerful principle for the chemists to create diversity and originality from simple molecules. Carbophilic late transition metals such as gold or platinum have appeared as fascinating catalysts able to activate alkenes, alkynes and other unsaturated derivatives towards anti nucleophilic addition via complexation on a single empty coordination site. Tunable chiral square-planar cationic platinum complexes created by combination of a mono- and a bidentate ligand appear as a new class of highly promising asymmetric catalytic systems. This highlight intends to stress the potential applications in enantioselective catalytic reactions associated with a variety of chiral cationic tricoordinated platinum complexes recently described in the literature.
Keywords: alkene, alkyne, asymmetric catalysis, cationic and carbophilic complexes, cycloisomerization reaction, enyne, Lewis acid, platinum
Current Organic Chemistry
Title: Chiral Cationic Platinum Complexes: New Catalysts for The Activation of Carbon-Carbon Multiple Bonds Towards Nucleophilic Enantioselective Attack
Volume: 14 Issue: 12
Author(s): Patrick Y. Toullec and Veronique Michelet
Affiliation:
Keywords: alkene, alkyne, asymmetric catalysis, cationic and carbophilic complexes, cycloisomerization reaction, enyne, Lewis acid, platinum
Abstract: The concept of π-acid catalysis has emerged as a powerful principle for the chemists to create diversity and originality from simple molecules. Carbophilic late transition metals such as gold or platinum have appeared as fascinating catalysts able to activate alkenes, alkynes and other unsaturated derivatives towards anti nucleophilic addition via complexation on a single empty coordination site. Tunable chiral square-planar cationic platinum complexes created by combination of a mono- and a bidentate ligand appear as a new class of highly promising asymmetric catalytic systems. This highlight intends to stress the potential applications in enantioselective catalytic reactions associated with a variety of chiral cationic tricoordinated platinum complexes recently described in the literature.
Export Options
About this article
Cite this article as:
Y. Toullec Patrick and Michelet Veronique, Chiral Cationic Platinum Complexes: New Catalysts for The Activation of Carbon-Carbon Multiple Bonds Towards Nucleophilic Enantioselective Attack, Current Organic Chemistry 2010; 14 (12) . https://dx.doi.org/10.2174/138527210791330431
DOI https://dx.doi.org/10.2174/138527210791330431 |
Print ISSN 1385-2728 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-5348 |
Call for Papers in Thematic Issues
Advances of Heterocyclic Chemistry with Pesticide Activity
Global food safety and security will continue to be a global concern for the next 50 years and beyond. Plant diseases have had a significant impact on food safety and security throughout the entire food chain, from primary production to consumption. While conventional chemical pesticides have been traditionally used for ...read more
Calculation design of covalent/metal organic framework based catalysts
This research area combines theoretical computation and screening with machine learning for the design of covalent/metal organic framework-based catalysts, bridging the disciplines of organic chemistry, physical chemistry, computational chemistry, materials science, and machine learning. It covers several critical aspects: designing and synthesizing organic catalysts for improved performance, applying computational methods ...read more
Carbohydrates conversion in biofuels and bioproducts
Biomass pretreatment, hydrolysis, and saccharification of carbohydrates, and sugars bioconversion in biofuels and bioproducts within a biorefinery framework. Carbohydrates derived from woody biomass, agricultural wastes, algae, sewage sludge, or any other lignocellulosic feedstock are included in this issue. Simulation, techno-economic analysis, and life cycle analysis of a biorefinery process are ...read more
Catalytic C-H bond activation as a tool for functionalization of heterocycles
The major topic is the functionalization of heterocycles through catalyzed C-H bond activation. The strategies based on C-H activation not only provide straightforward formation of C-C or C-X bonds but, more importantly, allow for the avoidance of pre-functionalization of one or two of the cross-coupling partners. The beneficial impact of ...read more
Related Journals
- Author Guidelines
- Graphical Abstracts
- Fabricating and Stating False Information
- Research Misconduct
- Post Publication Discussions and Corrections
- Publishing Ethics and Rectitude
- Increase Visibility of Your Article
- Archiving Policies
- Peer Review Workflow
- Order Your Article Before Print
- Promote Your Article
- Manuscript Transfer Facility
- Editorial Policies
- Allegations from Whistleblowers
- Announcements