Recent Advance in Asymmetric Alkynylation of Ketones

Author(s): Li Lin, Rui Wang.

Journal Name: Current Organic Chemistry

Volume 13 , Issue 15 , 2009

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Abstract:

Asymmetric alkynylation of ketones can provide versatile chiral tertiary propargylic alcohols. A series of strategies have been achieved in the past few years. Relative optimal reaction conditions for obtaining the highest enantioselectivities and yields, as well as the practical scope of different types of catalytic systems are reviewed.

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Article Details

VOLUME: 13
ISSUE: 15
Year: 2009
Page: [1565 - 1576]
Pages: 12
DOI: 10.2174/138527209789177725
Price: $58

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