Dehydrogenative Bond-Forming Catalysis Involving Phosphines

Author(s): Rory Waterman.

Journal Name: Current Organic Chemistry

Volume 12 , Issue 15 , 2008

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Abstract:

This review presents developments in the young field of dehydrogenative coupling reactions of phosphines. Catalytic phosphorus – element bond formation via dehydrocoupling has rapidly expanded since the first discoveries in the mid 1990s. A survey of the available catalysts, P – P and P – E products, and mechanistic understanding is presented with emphasis on the emerging synthetic applications of this reaction.

Keywords: dehydrogenative, phosphines, Catalytic phosphorus, –, element, dehydrocoupling, catalysts

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Article Details

VOLUME: 12
ISSUE: 15
Year: 2008
Page: [1322 - 1339]
Pages: 18
DOI: 10.2174/138527208785909592
Price: $58

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