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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Zamojskis Total Synthesis of Racemic Monosaccharides as an Inspiration for Stereoselective Transformations of Readily Available Sugar Synthons

Author(s): Marek Chmielewski, Sebastian Stecko and Wioletta Kosnik

Volume 12, Issue 12, 2008

Page: [973 - 984] Pages: 12

DOI: 10.2174/138527208785161150

Price: $65

Abstract

The present account reports on the E-α,β-unsaturated-δ-butoxycarbonyl-δ-hydroxy-aldehyde (3), acetal hydroperoxide (4) and α,β-unsaturated-δ-lactone (5), obtained during Zamojskis total synthesis of carbohydrates. Properties of these and related compounds, and their further applications in organic synthesis are discussed.

Keywords: Zamojski's Total Synthesis, Racemic Monosaccharides, Stereoselective Transformations, Sugar Synthons, carbohydrates, organic synthesis, Anomeric Hydroperoxides


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