Zamojskis Total Synthesis of Racemic Monosaccharides as an Inspiration for Stereoselective Transformations of Readily Available Sugar Synthons

Author(s): Marek Chmielewski, Sebastian Stecko, Wioletta Kosnik.

Journal Name: Current Organic Chemistry

Volume 12 , Issue 12 , 2008

Abstract:

The present account reports on the E-α,β-unsaturated-δ-butoxycarbonyl-δ-hydroxy-aldehyde (3), acetal hydroperoxide (4) and α,β-unsaturated-δ-lactone (5), obtained during Zamojskis total synthesis of carbohydrates. Properties of these and related compounds, and their further applications in organic synthesis are discussed.

Keywords: Zamojski's Total Synthesis, Racemic Monosaccharides, Stereoselective Transformations, Sugar Synthons, carbohydrates, organic synthesis, Anomeric Hydroperoxides

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Article Details

VOLUME: 12
ISSUE: 12
Year: 2008
Page: [973 - 984]
Pages: 12
DOI: 10.2174/138527208785161150
Price: $58

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